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alt="zmd.jpg"/></p><p><br/></p><p><strong>背景</strong></p><p>陜西某大型煤化工120萬(wàn)噸/年煤制烯烴項目配套有三套循環(huán)水系統，合計流量120000m3/h,于2013年底投入冷態(tài)運行。循環(huán)水系統的水質(zhì)處理先后國內外幾家水處理公司進(jìn)行處理，其中不乏國際公司。</p><p><strong>問(wèn) 題</strong></p><p>由于循環(huán)水負荷較低，基本處于冷態(tài)運行，加上水處理不了解系統工藝及特點(diǎn)，導致水處理效果很差，循環(huán)水系統腐蝕率嚴重超標，循環(huán)水鐵離子一度高達8ppm,循環(huán)水整體出現“紅水”現象，各個(gè)水處理公司頻繁更換各種藥劑，也未解決。某國際知名水處理公司對其中一套循環(huán)水進(jìn)行了預膜處理，也未控制住系統的腐蝕。嚴重的影響業(yè)主的設備安全，給業(yè)主今后的生產(chǎn)帶來(lái)隱患。如果不及時(shí)加以控制，水的問(wèn)題給整個(gè)業(yè)主帶來(lái)了巨大的經(jīng)濟損失。</p><p><strong>方案</strong></p><p>全澤化工技術(shù)工程師多次對該系統進(jìn)行調查研究，并對水質(zhì)、流量及工藝進(jìn)行跟蹤監測，提出了針對性的解決方案。</p><p>①　清洗預膜：鑒于循環(huán)水系統鐵離子均高達4~8ppm，業(yè)主廠(chǎng)處于陜西沙漠地區，水資源匱乏，加上環(huán)保壓力，不可能提供大量的水資源供傳統清洗預膜方案的水質(zhì)置換，在這種苛刻的條件下，某國際知名水處理公司認為方案無(wú)法實(shí)施，退出競爭。我公司針對現場(chǎng)情況，提出了顛覆性的方案--居于高鐵情況下的清洗預膜一體化方案，使用含有特殊成分的清洗預膜劑ML-220A，預膜增效劑ML-220B及高效鐵離子分散劑ML-325，在少量水質(zhì)置換的情況下很好的完成了清洗預膜，清洗預膜后鐵離子持續下降，保持在1.0ppm以?xún)龋?/p><p>②　冷態(tài)運行方案：循環(huán)水的負荷較低，濃縮倍數低，補水水質(zhì)的多樣性，針對性使用緩蝕性能優(yōu)異的緩蝕劑ML-425A，同時(shí)兼顧系統的沉積及結垢控制，連續投加阻垢分散劑ML-425B，同時(shí)考慮系統銅合金的防腐，連續投加高效銅緩蝕劑ML-D-06H，配合定期投加氧化殺菌劑，非氧化殺菌劑ML-630，控制菌藻滋生。</p><p>③　正常運行方案; 生產(chǎn)負荷逐漸上升后，循環(huán)水濃縮倍數迅速提升至5.0左右，系統結垢傾向增強，連續投加高性能阻垢分散劑ML-425C，同時(shí)兼顧系統的腐蝕控制，連續投加緩蝕阻垢劑ML-425D,和銅緩蝕劑ML-D-06H，定期定期投加氧化殺菌劑，非氧化殺菌劑ML-630，控制菌藻滋生，階段性投加無(wú)泡型粘泥剝離劑ML-624，保持系統的清潔性。</p><p>④　泄漏應急方案; 煤化工生產(chǎn)難免出現介質(zhì)泄漏，我公司派駐一支經(jīng)驗豐富的技術(shù)服務(wù)工程駐點(diǎn)業(yè)主單位，能夠及時(shí)預判循環(huán)水發(fā)生的各種問(wèn)題，及時(shí)發(fā)現循環(huán)水異常情況，快速提出解決方案并解決。</p><p><strong>效果</strong></p><p>在多方共同努力下，循環(huán)水水質(zhì)大大改善，監測腐蝕率遠遠小于國標規定的標準。在系統產(chǎn)生泄漏等特殊情況下，能夠及時(shí)的發(fā)現問(wèn)題的根本所在，及時(shí)的給予解決。</p><p> 循環(huán)水腐蝕率</p><p style="text-align: center;"><img src="/upfile/202012/2020122560125685.png" title="2015091555192437.png" alt="2015091555192437.png"/> <img src="/upfile/202012/2020122560131485.png" title="201509:2015091555196109.png" alt="201509:2015091555196109.png"/></p><p><strong>投資回報</strong><br/></p><p>在我公司運行總包的一年里，基本保持濃縮倍數在5.0以上，與設計相比全年累計節約新水500萬(wàn)噸，單這一項給業(yè)主帶來(lái)數千萬(wàn)的經(jīng)濟效益，綜上所述，全澤化工水處理方案及服務(wù)為業(yè)主創(chuàng )造了巨大的經(jīng)濟效益和社會(huì )效應。</p><p><br/></p> <div id="ppdjztr" 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